Document Text Contents
Page 1
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
CITADEL DIAMOND WRAP STANDARD PRIMER RESIN
STATEMENT OF HAZARDOUS NATURE
CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200.
NFPA
SUPPLIER
Chemwatch Pty Ltd
+61 3 9573 3112 or (where available) Toll Free +800 2436 2255
Email [email protected]
Email: [email protected]
PRODUCT USE
» Used according to manufacturer's directions.
SYNONYMS
"Bisphenol A Epoxy Resin Compound"
Section 2 - HAZARDS IDENTIFICATION
CHEMWATCH HAZARD RATINGS
CANADIAN WHMIS SYMBOLS
EMERGENCY OVERVIEW
RISK
May cause SENSITISATION by skin contact.
Irritating to eyes and skin.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
» Although ingestion is not thought to produce harmful effects, the material may still be damaging to the health of the individual following
ingestion, especially where pre-existing organ (e.g. liver, kidney) damage is evident.
<\p>.
EYE
» This material can cause eye irritation and damage in some persons.
SKIN
» Skin contact is not thought to have harmful health effects, however the material may still produce health damage following entry through wounds,
lesions or abrasions.
INHALED
» The material is not thought to produce adverse health effects or irritation of the respiratory tract (as classified using animal models).
Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable control measures be used in an occupational setting.
CHRONIC HEALTH EFFECTS
» Skin contact with the material is more likely to cause a sensitization reaction in some persons compared to the general population.
Sensitization may give severe responses to very low levels of exposure, i.e. hypersensitivity.
<\p>.
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
Section 4 - FIRST AID MEASURES
SWALLOWED
CITADEL DIAMOND WRAP STANDARD PRIMER RESIN
Chemwatch Material Safety Data Sheet
Jun-2-2009
C!293TC
CHEMWATCH 15-9237
Version No:2.0
Flammability 1
Toxicity 2
Body Contact 2
Reactivity 1
Chronic 2
SCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4
NAME CAS RN %
bisphenol A/ epichlorohydrin resin, liquid 25068-38-6 >60
(C12- 14)alkylglycidyl ether 68609-97-2 <16
additives <10
Page 1 of 5Chemwatch MSDS
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Page 2
· If swallowed do NOT induce vomiting.
· If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration.
EYE
» If this product comes in contact with the eyes:
· Immediately hold eyelids apart and flush the eye continuously with running water.
· Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids.
SKIN
» If skin contact occurs:
· Immediately remove all contaminated clothing, including footwear
· Flush skin and hair with running water (and soap if available).
INHALED
· If fumes or combustion products are inhaled remove from contaminated area.
· Lay patient down. Keep warm and rested.
NOTES TO PHYSICIAN
» Treat symptomatically.
Section 5 - FIRE FIGHTING MEASURES
Flash Point (ºF): >199.4
Lower Explosive Limit (%): Not Available
Upper Explosive Limit (%): Not Available
Autoignition Temp (ºF): Not Available
EXTINGUISHING MEDIA
· Foam.
· Dry chemical powder.
FIRE FIGHTING
· Alert Emergency Responders and tell them location and nature of hazard.
· Wear breathing apparatus plus protective gloves.
GENERAL FIRE HAZARDS/HAZARDOUS COMBUSTIBLE PRODUCTS
· Combustible.
· Slight fire hazard when exposed to heat or flame.
Combustion products include: carbon dioxide (CO2), other pyrolysis products typical of burning organic material.
May emit poisonous fumes.
FIRE INCOMPATIBILITY
» Avoid contamination with oxidizing agents i.e. nitrates, oxidizing acids,chlorine bleaches, pool chlorine etc. as ignition may result.
Personal Protective Equipment
Gas tight chemical resistant suit.
Section 6 - ACCIDENTAL RELEASE MEASURES
MINOR SPILLS
» Environmental hazard - contain spillage.
· Remove all ignition sources.
· Clean up all spills immediately.
MAJOR SPILLS
» Environmental hazard - contain spillage.
Moderate hazard.
· Clear area of personnel and move upwind.
· Alert Emergency Responders and tell them location and nature of hazard.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
· DO NOT allow clothing wet with material to stay in contact with skin.
· Avoid all personal contact, including inhalation.
· Wear protective clothing when risk of exposure occurs.
RECOMMENDED STORAGE METHODS
· Metal can or drum
· Packing as recommended by manufacturer.
STORAGE REQUIREMENTS
· Store in original containers.
· Keep containers securely sealed.
· No smoking, naked lights or ignition sources.
· Store in a cool, dry, well-ventilated area.
· Store away from incompatible materials and foodstuff containers.
· Protect containers against physical damage and check regularly for leaks.
· Observe manufacturer's storing and handling recommendations.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
PERSONAL PROTECTION
RESPIRATOR
Type A-P Filter of sufficient capacity
Consult your EHS staff for recommendations
EYE
· Safety glasses with side shields.
· Chemical goggles.
• bisphenol A/ epichlorohydrin resin, liquid: CAS:25068-38-6 CAS:25085-99-8
• (C12-14)alkylglycidyl ether: CAS:68609-97-2
Page 2 of 5Chemwatch MSDS
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Page 4
Section 13 - DISPOSAL CONSIDERATIONS
Disposal Instructions
All waste must be handled in accordance with local, state and federal regulations.
· Recycle wherever possible or consult manufacturer for recycling options.
· Consult Waste Management Authority for disposal.
Section 14 - TRANSPORTATION INFORMATION
DOT:
Hazardous materials descriptions and proper shipping names:
Environmentally hazardous substance, liquid, n.o.s
Air Transport IATA:
Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. *(CONTAINS BISPHENOL A/ EPICHLOROHYDRIN RESIN,
LIQUID (C12-14)ALKYLGLYCIDYL ETHER)
Maritime Transport IMDG:
Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.(contains bisphenol A/ epichlorohydrin resin, liquid
(C12-14)alkylglycidyl ether)
Section 15 - REGULATORY INFORMATION
REGULATIONS
Citadel Diamond Wrap Standard Primer Resin (CAS: None):
No regulations applicable
Regulations for ingredients
bisphenol A/ epichlorohydrin resin, liquid (CAS: 25068-38-6) is found on the following regulatory lists;
Canada Toxicological Index Service - Workplace Hazardous Materials Information System - WHMIS
Canada Toxicological Index Service - Workplace Hazardous Materials Information System - WHMIS (French)
OECD Representative List of High Production Volume (HPV) Chemicals
US - Minnesota Hazardous Substance List
US DOE Temporary Emergency Exposure Limits (TEELs)
US FDA Indirect Food Additives: Adhesives and Components of Coatings - Substances for Use Only as Components of Adhesives - Adhesives
US Toxic Substances Control Act (TSCA) - Inventory
bisphenol A/ epichlorohydrin resin, liquid (CAS: 25085-99-8) is found on the following regulatory lists;
Canada Domestic Substances List (DSL)
OECD Representative List of High Production Volume (HPV) Chemicals
US - Minnesota Hazardous Substance List
US Toxic Substances Control Act (TSCA) - Inventory
US TSCA Section 8 (d) - Health and Safety Data Reporting
(C12-14)alkylglycidyl ether (CAS: 68609-97-2) is found on the following regulatory lists;
OECD Representative List of High Production Volume (HPV) Chemicals
US - Minnesota Hazardous Substance List
US EPA High Production Volume Program Chemical List
US EPA Master Testing List - Index I Chemicals Listed
US Toxic Substances Control Act (TSCA) - Inventory
US TSCA Section 4 - Chemicals Subject to Testing Consent Orders
US TSCA Section 4/12 (b) - Sunset Date/Status
US TSCA Section 8 (d) - Health and Safety Data Reporting
Section 16 - OTHER INFORMATION
LIMITED EVIDENCE
» Ingestion may produce health damage*.
» Cumulative effects may result following exposure*.
» May produce discomfort of the respiratory system*.
» Limited evidence of a carcinogenic effect*.
» Possible respiratory sensitizer*.
» May possibly affect fertility*.
* (limited evidence).
INGREDIENTS WITH MULTIPLE CAS NUMBERS
epichlorohydrin
resin,
liquid
HIGH
No
data
LOW HIGH
(C12-
14)
alkylglycidyl
ether
No
data
Symbols: G Hazard class or Division: 9
Identification Numbers: UN3082 PG: III
Label Codes: 9 Special provisions: 8, 146, 335, IB3, T4, TP1, TP29
Packaging: Exceptions: 203 Packaging: Non-bulk: 241
Packaging: Exceptions: 203 Quantity limitations: Passenger aircraft/rail: No limit
Quantity Limitations: Cargo aircraft only: No limit Vessel stowage: Location: A
Vessel stowage: Other: None
ICAO/IATA Class: 9 ICAO/IATA Subrisk: None
UN/ID Number: 3082 Packing Group: III
Special provisions: A97
IMDG Class: 9 IMDG Subrisk: None
UN Number: 3082 Packing Group: III
EMS Number: F-A,S-F Special provisions: 274 909 944
Limited Quantities: 5 L Marine Pollutant: Not Determined
Ingredient Name CAS
Page 4 of 5Chemwatch MSDS
2/26/2010file://C:\Users\Matt Green\Documents\CHEM\Citadel Diamond Wrap Standard Primer Re...
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
CITADEL DIAMOND WRAP STANDARD PRIMER RESIN
STATEMENT OF HAZARDOUS NATURE
CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200.
NFPA
SUPPLIER
Chemwatch Pty Ltd
+61 3 9573 3112 or (where available) Toll Free +800 2436 2255
Email [email protected]
Email: [email protected]
PRODUCT USE
» Used according to manufacturer's directions.
SYNONYMS
"Bisphenol A Epoxy Resin Compound"
Section 2 - HAZARDS IDENTIFICATION
CHEMWATCH HAZARD RATINGS
CANADIAN WHMIS SYMBOLS
EMERGENCY OVERVIEW
RISK
May cause SENSITISATION by skin contact.
Irritating to eyes and skin.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
» Although ingestion is not thought to produce harmful effects, the material may still be damaging to the health of the individual following
ingestion, especially where pre-existing organ (e.g. liver, kidney) damage is evident.
<\p>.
EYE
» This material can cause eye irritation and damage in some persons.
SKIN
» Skin contact is not thought to have harmful health effects, however the material may still produce health damage following entry through wounds,
lesions or abrasions.
INHALED
» The material is not thought to produce adverse health effects or irritation of the respiratory tract (as classified using animal models).
Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable control measures be used in an occupational setting.
CHRONIC HEALTH EFFECTS
» Skin contact with the material is more likely to cause a sensitization reaction in some persons compared to the general population.
Sensitization may give severe responses to very low levels of exposure, i.e. hypersensitivity.
<\p>.
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
Section 4 - FIRST AID MEASURES
SWALLOWED
CITADEL DIAMOND WRAP STANDARD PRIMER RESIN
Chemwatch Material Safety Data Sheet
Jun-2-2009
C!293TC
CHEMWATCH 15-9237
Version No:2.0
Flammability 1
Toxicity 2
Body Contact 2
Reactivity 1
Chronic 2
SCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4
NAME CAS RN %
bisphenol A/ epichlorohydrin resin, liquid 25068-38-6 >60
(C12- 14)alkylglycidyl ether 68609-97-2 <16
additives <10
Page 1 of 5Chemwatch MSDS
2/26/2010file://C:\Users\Matt Green\Documents\CHEM\Citadel Diamond Wrap Standard Primer Re...
Page 2
· If swallowed do NOT induce vomiting.
· If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration.
EYE
» If this product comes in contact with the eyes:
· Immediately hold eyelids apart and flush the eye continuously with running water.
· Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids.
SKIN
» If skin contact occurs:
· Immediately remove all contaminated clothing, including footwear
· Flush skin and hair with running water (and soap if available).
INHALED
· If fumes or combustion products are inhaled remove from contaminated area.
· Lay patient down. Keep warm and rested.
NOTES TO PHYSICIAN
» Treat symptomatically.
Section 5 - FIRE FIGHTING MEASURES
Flash Point (ºF): >199.4
Lower Explosive Limit (%): Not Available
Upper Explosive Limit (%): Not Available
Autoignition Temp (ºF): Not Available
EXTINGUISHING MEDIA
· Foam.
· Dry chemical powder.
FIRE FIGHTING
· Alert Emergency Responders and tell them location and nature of hazard.
· Wear breathing apparatus plus protective gloves.
GENERAL FIRE HAZARDS/HAZARDOUS COMBUSTIBLE PRODUCTS
· Combustible.
· Slight fire hazard when exposed to heat or flame.
Combustion products include: carbon dioxide (CO2), other pyrolysis products typical of burning organic material.
May emit poisonous fumes.
FIRE INCOMPATIBILITY
» Avoid contamination with oxidizing agents i.e. nitrates, oxidizing acids,chlorine bleaches, pool chlorine etc. as ignition may result.
Personal Protective Equipment
Gas tight chemical resistant suit.
Section 6 - ACCIDENTAL RELEASE MEASURES
MINOR SPILLS
» Environmental hazard - contain spillage.
· Remove all ignition sources.
· Clean up all spills immediately.
MAJOR SPILLS
» Environmental hazard - contain spillage.
Moderate hazard.
· Clear area of personnel and move upwind.
· Alert Emergency Responders and tell them location and nature of hazard.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
· DO NOT allow clothing wet with material to stay in contact with skin.
· Avoid all personal contact, including inhalation.
· Wear protective clothing when risk of exposure occurs.
RECOMMENDED STORAGE METHODS
· Metal can or drum
· Packing as recommended by manufacturer.
STORAGE REQUIREMENTS
· Store in original containers.
· Keep containers securely sealed.
· No smoking, naked lights or ignition sources.
· Store in a cool, dry, well-ventilated area.
· Store away from incompatible materials and foodstuff containers.
· Protect containers against physical damage and check regularly for leaks.
· Observe manufacturer's storing and handling recommendations.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
PERSONAL PROTECTION
RESPIRATOR
Type A-P Filter of sufficient capacity
Consult your EHS staff for recommendations
EYE
· Safety glasses with side shields.
· Chemical goggles.
• bisphenol A/ epichlorohydrin resin, liquid: CAS:25068-38-6 CAS:25085-99-8
• (C12-14)alkylglycidyl ether: CAS:68609-97-2
Page 2 of 5Chemwatch MSDS
2/26/2010file://C:\Users\Matt Green\Documents\CHEM\Citadel Diamond Wrap Standard Primer Re...
Page 4
Section 13 - DISPOSAL CONSIDERATIONS
Disposal Instructions
All waste must be handled in accordance with local, state and federal regulations.
· Recycle wherever possible or consult manufacturer for recycling options.
· Consult Waste Management Authority for disposal.
Section 14 - TRANSPORTATION INFORMATION
DOT:
Hazardous materials descriptions and proper shipping names:
Environmentally hazardous substance, liquid, n.o.s
Air Transport IATA:
Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. *(CONTAINS BISPHENOL A/ EPICHLOROHYDRIN RESIN,
LIQUID (C12-14)ALKYLGLYCIDYL ETHER)
Maritime Transport IMDG:
Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.(contains bisphenol A/ epichlorohydrin resin, liquid
(C12-14)alkylglycidyl ether)
Section 15 - REGULATORY INFORMATION
REGULATIONS
Citadel Diamond Wrap Standard Primer Resin (CAS: None):
No regulations applicable
Regulations for ingredients
bisphenol A/ epichlorohydrin resin, liquid (CAS: 25068-38-6) is found on the following regulatory lists;
Canada Toxicological Index Service - Workplace Hazardous Materials Information System - WHMIS
Canada Toxicological Index Service - Workplace Hazardous Materials Information System - WHMIS (French)
OECD Representative List of High Production Volume (HPV) Chemicals
US - Minnesota Hazardous Substance List
US DOE Temporary Emergency Exposure Limits (TEELs)
US FDA Indirect Food Additives: Adhesives and Components of Coatings - Substances for Use Only as Components of Adhesives - Adhesives
US Toxic Substances Control Act (TSCA) - Inventory
bisphenol A/ epichlorohydrin resin, liquid (CAS: 25085-99-8) is found on the following regulatory lists;
Canada Domestic Substances List (DSL)
OECD Representative List of High Production Volume (HPV) Chemicals
US - Minnesota Hazardous Substance List
US Toxic Substances Control Act (TSCA) - Inventory
US TSCA Section 8 (d) - Health and Safety Data Reporting
(C12-14)alkylglycidyl ether (CAS: 68609-97-2) is found on the following regulatory lists;
OECD Representative List of High Production Volume (HPV) Chemicals
US - Minnesota Hazardous Substance List
US EPA High Production Volume Program Chemical List
US EPA Master Testing List - Index I Chemicals Listed
US Toxic Substances Control Act (TSCA) - Inventory
US TSCA Section 4 - Chemicals Subject to Testing Consent Orders
US TSCA Section 4/12 (b) - Sunset Date/Status
US TSCA Section 8 (d) - Health and Safety Data Reporting
Section 16 - OTHER INFORMATION
LIMITED EVIDENCE
» Ingestion may produce health damage*.
» Cumulative effects may result following exposure*.
» May produce discomfort of the respiratory system*.
» Limited evidence of a carcinogenic effect*.
» Possible respiratory sensitizer*.
» May possibly affect fertility*.
* (limited evidence).
INGREDIENTS WITH MULTIPLE CAS NUMBERS
epichlorohydrin
resin,
liquid
HIGH
No
data
LOW HIGH
(C12-
14)
alkylglycidyl
ether
No
data
Symbols: G Hazard class or Division: 9
Identification Numbers: UN3082 PG: III
Label Codes: 9 Special provisions: 8, 146, 335, IB3, T4, TP1, TP29
Packaging: Exceptions: 203 Packaging: Non-bulk: 241
Packaging: Exceptions: 203 Quantity limitations: Passenger aircraft/rail: No limit
Quantity Limitations: Cargo aircraft only: No limit Vessel stowage: Location: A
Vessel stowage: Other: None
ICAO/IATA Class: 9 ICAO/IATA Subrisk: None
UN/ID Number: 3082 Packing Group: III
Special provisions: A97
IMDG Class: 9 IMDG Subrisk: None
UN Number: 3082 Packing Group: III
EMS Number: F-A,S-F Special provisions: 274 909 944
Limited Quantities: 5 L Marine Pollutant: Not Determined
Ingredient Name CAS
Page 4 of 5Chemwatch MSDS
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